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Microsoft has release VB.NET samples for coding Metro UI apps in Windows 8.
Check them out now at these links:
Individual Downloads:
http://code.msdn.microsoft.com/windowsapps/site/search?f%5B0%5D.Type=ProgrammingLanguage&f%5B0%5D.Value=VB&f%5B0%5D.Text=VB.NET
Bulk Download of all samples:
http://code.msdn.microsoft.com/Windows-Developer-Preview-6b53adbb